Relativistic Effects on the Heavy Metal-ligand NMR Spin-spin Couplings

5/26/99


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Table of Contents

Relativistic Effects on the Heavy Metal-ligand NMR Spin-spin Couplings

Abstract

Introduction

Introduction

Nuclear spin-spin coupling through Fermi-contact

Nonrelativistic Fermi-contact contribution

Scalar relativistic correction scheme I and II

Couplings involving main-group metals

Couplings involving main-group metals

Couplings involving main-group metals

Couplings involving platinum

Couplings involving platinum

Couplings involving platinum

Trans influence and spin-spin coupling constants

Trans influence and spin-spin coupling constants

References

Acknowledgement

Author: Jana Khandogin and Tom Ziegler

Email: ykhandog@ucalgary.ca

Home Page: http://www.cobalt.chem.ucalgary.ca/khan

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