Start with the energy of a photon in terms of its frequency n.

The special theory of relativity gives a new expression in terms of the velocity of light. In this expression, m refers to the relativistic mass of light which is non-zero because it is travelling with velocity c - if it were at rest, it's mass would be zero.

Equate these two equations and recall the expression relating the frequency and wavelength of a photon.

By analogy, de Broglie argued that a particle with non-zero rest mass m and velocity v would have a wavelength given by

Since mv=p, where p is the particle's momentum, the now famous de Broglie relation becomes

To study this a bit more deeply, go to the Free Particle Model section in the Simple Model sections of this work.